Skip to main content
SpringerLink
Log in

Behavior of skeletal copper-palladium catalysts in enantioselective hydrogenation

  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    It has been established that skeletal Cu-Pd catalysts contain phases of Pd and Cu or a Pd-based solid solution, and also Pd, and Al2O3·3H2O.

  2. 2.

    The adsorption of hydrogen on these catalysts in a 0.1 N H2SO4 solution has been investigated, and it has been found that the quantity of hydrogen adsorbed on the skeletal copper-palladium catalysts drops off very rapidly as the Pd content in the Metallic phase is increased from 5.1% to 15.1% (at.).

  3. 3.

    The possibility of catalytic activation of the copper by the palladium has been demonstrated, and also the capability of the skeletal copper-palladium catalysts for performing enantioselective hydrogenation.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. E. I. Klabunovskii, A. A. Vedenyapin, G. Kh. Areshidze, and N. D. Zubareva, in: Proceedings of 4th Soviet-French Seminar on Catalysis [in Russian], Metsniereba., Tbilisi (1978), p. 173.

    Google Scholar 

  2. A. I. Stetsenko and I. P. Tverdovskii, Zh. Fiz, Khim.,26, 647 (1952).

    Google Scholar 

  3. Yu. A. Podvyazkin and A. I. Shlygin, Zh. Fiz. Khim.,31, 1305 (1957).

    Google Scholar 

  4. E. I. Klabunovskii, A. A. Vedenyapin, and G. Kh. Areshidze, Izv. Akad. Nauk SSSR, Ser. Khim., 2311 (1975).

Download references

Author information

Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    A. A. Vedenyapin, T. I. Kuznetsova, E. I. Klabunovskii, V. M. Akimov, N. B. Gorina, V. P. Polyakova & E. V. Zykova

Authors
  1. A. A. Vedenyapin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. T. I. Kuznetsova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. E. I. Klabunovskii
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. V. M. Akimov
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. N. B. Gorina
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. V. P. Polyakova
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. E. V. Zykova
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2206–2210, October, 1983.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Vedenyapin, A.A., Kuznetsova, T.I., Klabunovskii, E.I. et al. Behavior of skeletal copper-palladium catalysts in enantioselective hydrogenation. Russ Chem Bull 32, 1990–1994 (1983). https://doi.org/10.1007/BF00955755

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00955755

Keywords

Search

Navigation