Conclusions
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1.
Reduction potentials in the polarographic reduction of multicentered rhenium and osmium carbonyl halides with cross-linking halogen atoms depend only slightly on the nature of the halogen atom.
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2.
The effect of n-donor compounds on complexes of the (μ-X)2Os3(CO)10 type is to cause substitution of the CO groups at the osmium atoms and to conserve Os2X2 metal ring.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2187–2191, October, 1983.
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Trukhacheva, V.A., Burmakina, G.V., Gubin, S.P. et al. Polarographic reduction of rhenium and osmium carbonyl halides with halogen cross-links. Russ Chem Bull 32, 1973–1976 (1983). https://doi.org/10.1007/BF00955752
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DOI: https://doi.org/10.1007/BF00955752