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Solubility characteristics of poly(N-vinylcarbazole) prepared by Co(II) loaded 13X molecular sieve

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Abstract

During the polymerization of N-vinylcarbazole (NVC) by Co(II)-13X the resultant polymer (¯Mn=6000) is soluble in benzene or toluene but partly soluble in methylethyl ketone (MEK). To ascertain whether the MEK insolubility is due to polymer tacticity, the polymer has been further characterized by13C NMR analysis. The atactic structure of polyN-vinylcarbazole (PNVC) initiated by Co(II) has been established from a comparison of methine carbon (

) peaks with the same for a cationic PNVC(BF3/Et2O, isotactic) and radical PNVC (AIBN, atactic).

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Authors and Affiliations

  1. Department of Chemistry, Indian Institute of Technology, 721302, Kharagpur, India

    Madhusudan Banerjee & Mukul Biswas

  2. Materials Science Centre, Indian Institute of Technology, 721302, Kharagpur, India

    Mrinal M. Maiti

Authors
  1. Madhusudan Banerjee
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  2. Mukul Biswas
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  3. Mrinal M. Maiti
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Banerjee, M., Biswas, M. & Maiti, M.M. Solubility characteristics of poly(N-vinylcarbazole) prepared by Co(II) loaded 13X molecular sieve. Polymer Bulletin 16, 473–477 (1986). https://doi.org/10.1007/BF00955581

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  • DOI: https://doi.org/10.1007/BF00955581

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