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Oxidative polymerization of phenols having trimethylsilyl groups

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Summary

Phenols 2-substituted with trimethylsilyl groups (1,2 and3) were oxidatively polymerized with 2,6-dimethylphenol (4) in the presence of a copper-pyridine catalyst to yield the corresponding poly(phenyleneoxide) copolymers. The polymerization mechanism was studied kinetically and spectroscopically.

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References

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Authors and Affiliations

  1. Department of Polymer Chemistry, Waseda University, 160, Tokyo, Japan

    S. H. Hyun, H. Nishide & E. Tsuchida

Authors
  1. S. H. Hyun
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  2. H. Nishide
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  3. E. Tsuchida
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Hyun, S.H., Nishide, H. & Tsuchida, E. Oxidative polymerization of phenols having trimethylsilyl groups. Polymer Bulletin 16, 395–400 (1986). https://doi.org/10.1007/BF00955569

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  • DOI: https://doi.org/10.1007/BF00955569

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