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Transformed steroids Communication 151. Mechanism of the condensation of Δ16-20-ketosteroids with S.S-diphenylsulfilimine

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

Taking 16-dehydrocorticosterone 16-acetate as am example, a new mode of stabilization of the intermediate products of addition of S,S-diphenylsulfilimine to 21-acetoxy-Δ16-20-ketosteroids has been observed, the steroidal S → M ylide (21-acetoxy-16α-S,S-diphenylsulfiliminopregn-4-en-11β,21-diol-3,20-dione) being formed.

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Literature cited

  1. A. V. Kamernitskii, Z. I. Istomina, A. M. Turuta, T. M. Fadeeva, and V. S. Él'yanov, Izv. Akad. Nauk SSSR, Ser. Khim., 2383 (1982).

  2. A. V. Kamernitzky (Kamernitskii), A. M. Turuta, Z. I. Istomina, and B. S. Elyanov (Él'yanov), Synthesis, 509 (1982).

  3. A. V. Kamernitskii, Z. I. Istomina, A. M. Turuta, B. S. Él'yanov, and A. A. Korobov, Izv. Akad. Nauk SSSR, Ser. Khim., 893 (1984).

  4. H. J. Kooreman, A. F. Marx, and D. Sijde, Synth. Coonm.,1, 81 (1971).

    Google Scholar 

  5. V. H. Vanrheenen and J. B. Heather, British Patent 2012768A (1979); Chem. Abstr.,91, 193,522g (1979).

    Google Scholar 

  6. N. N. Gireva, A. F. Mikhaleva, L. G. Gatsenko, and L. V. Steshina, Inventor's Certificate No. 819119; Byull. Izobret., No. 13 (1981).

  7. H. L. Gilchrist and C. J. Moody, Chem. Rev.,77, 409 (1977).

    Google Scholar 

  8. J. E. Huber, French Patent 1557005; Chem. Abstr.,73, 131,217f (1970).

    Google Scholar 

  9. N. Furukawa, T. Yoshimura, M. Ohtsu, T. Akasaka, and S. Oae, Tetrahedron,36, 73 (1980).

    Google Scholar 

  10. T. Yoshimura, T. Akasaka, N. Furukawa, and S. Oae, Heterocycles,7, 287 (1977).

    Google Scholar 

  11. N. Furukawa, S. Oae, and T. Yoshimura, Synthesis, 30 (1976).

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    A. V. Kamernitskii, A. M. Turuta, Z. I. Istomina, A. A. Korobov & B. S. Él'yanov

Authors
  1. A. V. Kamernitskii
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  2. A. M. Turuta
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  3. Z. I. Istomina
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  4. A. A. Korobov
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  5. B. S. Él'yanov
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1181–1184, May, 1986.

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Kamernitskii, A.V., Turuta, A.M., Istomina, Z.I. et al. Transformed steroids Communication 151. Mechanism of the condensation of Δ16-20-ketosteroids with S.S-diphenylsulfilimine. Russ Chem Bull 35, 1072–1075 (1986). https://doi.org/10.1007/BF00955384

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  • DOI: https://doi.org/10.1007/BF00955384

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