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Asymmetric nitrogen Communication 48. Geminal systems. communication 32 NH-dialkoxyamines: synthesis, mydroxy-and aminomethylation, nmr spectra, and configurational stability

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Alkaline hydrolysis of N,N-dialkoxy-N′,N′-dimethylureas gives NH-dialkoxyamines.

  2. 2.

    N-Hydroxymethyl- and N-aminomethyl-N,N,-dialkoxyamines have been synthesized and their reactions with nucleophiles and electrophiles have been studied.

  3. 3.

    The configurational stability of the N atom in NH-dialkoxyamines and their derivatives has been determined by NMR.

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Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow

    V. F. Rudchenko, S. M. Ignatov, I. I. Chervin, V. S. Nosova & R. G. Kostyanovskii

Authors
  1. V. F. Rudchenko
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  2. S. M. Ignatov
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  3. I. I. Chervin
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  4. V. S. Nosova
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  5. R. G. Kostyanovskii
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Additional information

For preceding communications, see [1].

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1153–1160, May, 1986.

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Rudchenko, V.F., Ignatov, S.M., Chervin, I.I. et al. Asymmetric nitrogen Communication 48. Geminal systems. communication 32 NH-dialkoxyamines: synthesis, mydroxy-and aminomethylation, nmr spectra, and configurational stability. Russ Chem Bull 35, 1045–1052 (1986). https://doi.org/10.1007/BF00955378

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  • DOI: https://doi.org/10.1007/BF00955378

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