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Hydrogenolysis of the C-Cl bond of the dichloromethylene group in polychloroalkanes initiated by Fe(CO)5, Mn2(CO)10, or tert-butyl peroxide in combination with triethylsilase

  • Organic Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

The dichloromethylene group in polychloroalkanes is selectively reduced by the action of Fe(CO)5, Mn2(CO)10 or (Me3CO)2O in combination with Et3SiH to a chloromethylene group. The Mn2(CO)10-Et3SiH system is the most efficient in this reaction.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    L. N. Kiseleva, N. A. Rybakova & R. Kh. Freidlina

Authors
  1. L. N. Kiseleva
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  2. N. A. Rybakova
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  3. R. Kh. Freidlina
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Translated from Izvestiya Akademii Nauk SSSK, Seriya Khimicheskaya, No. 5, pp. 1136–1138, May, 1986.

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Kiseleva, L.N., Rybakova, N.A. & Freidlina, R.K. Hydrogenolysis of the C-Cl bond of the dichloromethylene group in polychloroalkanes initiated by Fe(CO)5, Mn2(CO)10, or tert-butyl peroxide in combination with triethylsilase. Russ Chem Bull 35, 1030–1032 (1986). https://doi.org/10.1007/BF00955374

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  • DOI: https://doi.org/10.1007/BF00955374

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