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Hydrocarboxylation of olefins in the presence of Pd(II) complexes

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The rate and selectivity of hydrocarboxylation of terminal olefins in dioxane with catalysis by the PdCl2(PPh3)2-PPh3 system increases in the series C3 < C5 < C7, C9; under the mentioned conditions, the hydrocarboxylation of olefins with an internal double bond occurs significantly slower than the hydrocarboxylation of terminal olefins.

  2. 2.

    The replacement of PPh3 by SnCl2 promotes an increase of the rate and selectivity of hydrocarboxylation of terminal olefins by PdCl2(PPh3)2-SnCl2 system and sharply retards carbonylation of olefins with an internal double bond.

  3. 3.

    The side process of displacement of the double bond in 1-pentene practically does not affect the selectivity of hydrocarboxylation of this olefin in the presence of PdCl2· (PPh3)2-SnCl2

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Literature cited

  1. A, D. Karpyuk, M. I. Terekhova, N. D. Kolosova, É. S. Petrov, and I. P. Beletskaya, Izv. Akad. Nauk SSSR, Ser. Khim., 2291 (1984).

  2. M. I. Terekhova, A. D. Karpyuk, N. D. Kolosova, É. S. Petrov, and I. P. Beletskaya, Izv. Akad. Nauk SSSR, Ser. Khim., 2413 (1983).

  3. S. D. Pirozhkov, A. V. Dolidze, T. G. Alavidze, and A. L. Lapidus, 2nd All-Union Conference on Organometallic Chemistry. Abstracts of Papers [in Russian], Gorkii (1982), p. 348.

  4. F. J. Knifton, J. Org. Chem., 41, 793 (1976).

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Authors and Affiliations

  1. L. Ya. Karpov Physicochemical Institute, Moscow

    A. D. Karpyuk, É. S. Petrov & I. P. Beletskaya

Authors
  1. A. D. Karpyuk
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  2. É. S. Petrov
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  3. I. P. Beletskaya
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1134–1136, May, 1986.

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Karpyuk, A.D., Petrov, É.S. & Beletskaya, I.P. Hydrocarboxylation of olefins in the presence of Pd(II) complexes. Russ Chem Bull 35, 1028–1029 (1986). https://doi.org/10.1007/BF00955373

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  • DOI: https://doi.org/10.1007/BF00955373

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