Conclusions
The structure of 16α,17α-(acetylepimino)pregnenolone 3-acetate in the crystal and in solution has been investigated. The conformation of the 17β-acetyl group scarcely changes on passing from the crystalline state into solution.
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A. V. Kamernitskii and A. M. Turuta, Usp. Khim.,51, 1516 (1982).
A. V. Kamernitzky (Kamernitskii), I. S. Levina, L. E. Kulikova, V. N. Ignatov, V. V. Korkhov, G. V. Nikitina, and A. I. Terechina, J. Steroidal Biochem.,16, 61 (1982).
R. G. Gerr, A. I. Yanovskii, and Yu. T. Struchkov, Kristallografiya,28, 1029 (1983).
G. Snatzke, Optical Rotary Dispersion and Circular Dichroism in Organic Chemistry, Heyden and Sons, London (1967), p. 335.
W. L. Duax and D. A. Norton, Atlas of Steroid Structures, IFI/Plenum, New York, Vol. 1 (1975).
S. V. Lindeman, V. E. Shklover, Yu. T. Struchkov, A. V. Kamernitskii, I. G. Reshetova, and E. I. Chernoburova, Bioorg. Khim.,9, 1403 (1983).
W. B. Schweizer and J. D. Dunitz, Helv. Chim. Acta,65, 1547 (1982).
T. M. Ko, L. Olansky, and J. Moncrief, Acta Crystallogr.,B31, 1547 (1975).
I. P. Hazel, C. M. Weeks, and Y. Osawa, Cryst. Struct. Commun., 103 (1976).
Yu. T. Struchkov, V. E. Polishchuk, M. Yu. Antipin, A. V. Kamernitskii, and A. M. Turuta, Bioorg. Khim.,7, 779 (1981).
V. M. Tseikinskii, V. B. Rybakov, V. I. Simonov, A. V. Kamernitskii, V. N. Ignatov, and I. S. Levina, Bioorg. Khim.,6, 752 (1980).
I. N. Fundyler, A. V. Kamernitskii, and A. M. Turuta, Izv. Akad. Nauk SSSR, Ser. Khim., 2137 (1980).
Genkichi Ohta, Katsumi Koshi, and Kazunaga Obata, Chem. Pharm. Bull.,16, 1487 (1968).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1110–1116, May, 1986.
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Turuta, A.M., Kamernitskii, A.V., Lindeman, S.V. et al. Structure of 16α,17α-(Acetylepimino)pregnenolone 3-acetate in the crystal and in solution. Russ Chem Bull 35, 1006–1011 (1986). https://doi.org/10.1007/BF00955368
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DOI: https://doi.org/10.1007/BF00955368