Skip to main content
Log in

Investigation of free radicals and cation-radicals of phenoxazine, phenothiazine, and phenothiazine derivatives by EPR and electron-nuclear resonance

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

Double electron-nuclear resonance and triple electron-nuclear-nuclear resonance have been used for the first time to determine the HFS constants and their relative signs in free radicals and cation-radicals of phenoxazine, phenothiazine, and phenothiazine derivatives.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

Literature cited

  1. P. D. Sullivan and J. R. Bolton, J. Magn. Reson.,1, 356 (1969).

    Google Scholar 

  2. L. Ruperez, J. C. Conesa, and J. Soria, J. Chem. Soc. Perkin Trans., 2,12, 1517 (1982).

    Google Scholar 

  3. C. Jackson and N. K. D. Patel, Tetrahedron Lett., 2255 (1967).

  4. S. I. Weissman, E. De Boer, and J. J. Conradi, J. Chem. Phys.,26, 963 (1957).

    Google Scholar 

  5. W. F. Forbes and P. D. Sullivan, J. Am. Chem. Soc.,88, 2862 (1966).

    Google Scholar 

  6. D. Clarke, B. C. Gilbert, and P. Hanson, J. Chem. Soc. Perkin Trans. 2,1, 114 (1976).

    Google Scholar 

  7. D. Clarke, B. C. Gilbert, and P. Hanson, J. Chem. Soc. Perkin Trans. 2,4, 517 (1977).

    Google Scholar 

  8. D. Clarke, B. C. Gilbert, P. Hanson, and C. M. Kirk, J. Chem. Soc. Perkin Trans. 2,10, 1103 (1978).

    Google Scholar 

  9. F. Kehrmann and A. Neil Archibald, Ber. Deut. Chem. Ges.,47, 3102 (1914).

    Google Scholar 

  10. V. A. Skorodumov, É. M. Il'chenko, and S. V. Zhuravlev, Zh. Obshch. Khim.,30, 1680 (1960).

    Google Scholar 

  11. H. Gilman, R. D. Nelson, and J. F. Champaigne, J. Am. Chem. Soc.,74, 4205 (1952).

    Google Scholar 

  12. C. Bodea and M. Terdic, Studii Cercetari Chim. Acad. RPR, Fil. Cluji,12, No. 2 (1961); Chem. Abstr.,61, 4341 (1964).

  13. A. A. Shtyrlina, D. Kh. Yarmukhametova, K. M. Enikeev, I. É. Ismaev, and I. A. Nuretdinov, Izv. Akad. Nauk SSSR, Ser. Khim., 2361 (1983).

  14. K. Scheffler and H. B. Stegmann, Tetrahedron Lett., 3619 (1968).

  15. M. F. Chui, B. C. Gilbert, and P. Hanson, J. Chem. Soc. B,9, 1700 (1970).

    Google Scholar 

  16. J. M. Lhoste and F. Tonnard, J. Chim. Phys.,63, 678 (1966).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1094–1097, May, 1986.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kadirov, M.K., Il'yasov, A.V., Kamalov, R.M. et al. Investigation of free radicals and cation-radicals of phenoxazine, phenothiazine, and phenothiazine derivatives by EPR and electron-nuclear resonance. Russ Chem Bull 35, 991–993 (1986). https://doi.org/10.1007/BF00955364

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00955364

Keywords

Navigation