Conclusions
1-Substituted analogs of the perfluoromethallyl cation were prepared and characterized by13C and19F NMR spectroscopy. It was found that the cations studied exist in the form of Z, E isomers with respect to the\(C^1 \underset{\raise0.3em\hbox{$\smash{\scriptscriptstyle\cdots}$}}{---} C^2 \) bond.
Similar content being viewed by others
Literature cited
M. V. Galakhov, V. A. Petrov, V. I. Bakhmutov, G. G. Belen'kii, B. A. Kvasov, L. S. German, and É. I. Fedin, Izv. Akad. Nauk SSSR, Ser. Khim., 306 (1985).
V. A. Petrov, G. G. Belen'kii, M. V. Galakhov, V. I. Bakhmutov, L. S. German, and É. I. Fedin, Izv. Akad. Nauk SSSR, Ser. Khim., 2811 (1984).
M. V. Galakhov, V. A. Petrov, G. G. Belen'kii, V. I. Bakhmutov, L. S. German, and É. I. Fedin, Izv. Akad. Nauk SSSR, Ser. Khim., 1057 (1986).
J. W. Emsley, Z. Phillips, and Y. Wray, Progress in NMR Spectroscopy, Fluorine Coupling Constants, Pergamon Press, New York-London-Sydney-Toronto (1977), p. 85.
F. B. Mallory, C. B. Mallory, and M. C. Fedarco, J. Am. Chem. Soc.,96, 3536 (1974).
G. A. Olah, G. Laing, and Y. K. Mo, J. Org. Chero.,39, 2394 (1974).
G. A. Olah and R. J. Spear, J. Am. Chem. Soc.,97, 1539 (1975).
T. Shaefer, K. Marat, J. Peeling, and V. P. Verigin, Can. J. Chem.,61, 2779 (1983).
L. D. Kispert, C. U. Pitman, L. Allison, T. B. Peterson, S. W. Jilbert, C. F. Hiens, and J. Prather, J. Am. Chem. Soc.,84, 5979 (1972).
V. V. Tyuleneva, L. A. Rozov, Yu. V. Zeifman, and I. L. Knunyants, Izv. Akad. Nauk SSSR, Ser. Khim., 1136 (1975).
S. A. Posotovoi, Yu. V. Zeifman, and I. L. Knunyants, Izv. Akad. Nauk SSSR, SEr. Khim., 2826 (1982).
I. L. Knunyants, L. S. German, and B. L. Dyatkin, Izv. Akad. Nauk SSSR, Ser, Khim., 1353 (1956).
Author information
Authors and Affiliations
Additional information
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1063–1072, May, 1986.
Rights and permissions
About this article
Cite this article
Galakhov, M.V., Petrov, V.A., Belen'kii, G.G. et al. Structure and13C AND19F NMR spectra of 1-substituted analogs of perfluoromethallyl cation. Russ Chem Bull 35, 964–971 (1986). https://doi.org/10.1007/BF00955359
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00955359