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Structure and13C AND19F NMR spectra of 1-substituted analogs of perfluoromethallyl cation

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

1-Substituted analogs of the perfluoromethallyl cation were prepared and characterized by13C and19F NMR spectroscopy. It was found that the cations studied exist in the form of Z, E isomers with respect to the\(C^1 \underset{\raise0.3em\hbox{$\smash{\scriptscriptstyle\cdots}$}}{---} C^2 \) bond.

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Literature cited

  1. M. V. Galakhov, V. A. Petrov, V. I. Bakhmutov, G. G. Belen'kii, B. A. Kvasov, L. S. German, and É. I. Fedin, Izv. Akad. Nauk SSSR, Ser. Khim., 306 (1985).

  2. V. A. Petrov, G. G. Belen'kii, M. V. Galakhov, V. I. Bakhmutov, L. S. German, and É. I. Fedin, Izv. Akad. Nauk SSSR, Ser. Khim., 2811 (1984).

  3. M. V. Galakhov, V. A. Petrov, G. G. Belen'kii, V. I. Bakhmutov, L. S. German, and É. I. Fedin, Izv. Akad. Nauk SSSR, Ser. Khim., 1057 (1986).

  4. J. W. Emsley, Z. Phillips, and Y. Wray, Progress in NMR Spectroscopy, Fluorine Coupling Constants, Pergamon Press, New York-London-Sydney-Toronto (1977), p. 85.

    Google Scholar 

  5. F. B. Mallory, C. B. Mallory, and M. C. Fedarco, J. Am. Chem. Soc.,96, 3536 (1974).

    Google Scholar 

  6. G. A. Olah, G. Laing, and Y. K. Mo, J. Org. Chero.,39, 2394 (1974).

    Google Scholar 

  7. G. A. Olah and R. J. Spear, J. Am. Chem. Soc.,97, 1539 (1975).

    Google Scholar 

  8. T. Shaefer, K. Marat, J. Peeling, and V. P. Verigin, Can. J. Chem.,61, 2779 (1983).

    Google Scholar 

  9. L. D. Kispert, C. U. Pitman, L. Allison, T. B. Peterson, S. W. Jilbert, C. F. Hiens, and J. Prather, J. Am. Chem. Soc.,84, 5979 (1972).

    Google Scholar 

  10. V. V. Tyuleneva, L. A. Rozov, Yu. V. Zeifman, and I. L. Knunyants, Izv. Akad. Nauk SSSR, Ser. Khim., 1136 (1975).

  11. S. A. Posotovoi, Yu. V. Zeifman, and I. L. Knunyants, Izv. Akad. Nauk SSSR, SEr. Khim., 2826 (1982).

  12. I. L. Knunyants, L. S. German, and B. L. Dyatkin, Izv. Akad. Nauk SSSR, Ser, Khim., 1353 (1956).

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1063–1072, May, 1986.

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Galakhov, M.V., Petrov, V.A., Belen'kii, G.G. et al. Structure and13C AND19F NMR spectra of 1-substituted analogs of perfluoromethallyl cation. Russ Chem Bull 35, 964–971 (1986). https://doi.org/10.1007/BF00955359

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  • DOI: https://doi.org/10.1007/BF00955359

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