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Influence of a substituent at the 2 position on the stability of fluorine-containing allyl cations according to19F NMR spectroscopy data

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    It was shown for the first time that the thermodynamic stability of fluorine-containing cations depends on the substituent at the 2 position.

  2. 2.

    In the series studied, the 2-hydroperfluoroallyl cation has the highest thermodynamic stability, and the perfluoromethallyl cation the lowest.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Heteroorganlc Compounds, Academy of Sciences of the USSR, Moscow

    M. V. Galakhov, V. A. Petrov, G. G. Belen'kii, V. I. Bakhmutov, L. S. German & É. I. Fedin

Authors
  1. M. V. Galakhov
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  2. V. A. Petrov
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  3. G. G. Belen'kii
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  4. V. I. Bakhmutov
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  5. L. S. German
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  6. É. I. Fedin
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1057–1063, May, 1986.

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Galakhov, M.V., Petrov, V.A., Belen'kii, G.G. et al. Influence of a substituent at the 2 position on the stability of fluorine-containing allyl cations according to19F NMR spectroscopy data. Russ Chem Bull 35, 959–964 (1986). https://doi.org/10.1007/BF00955358

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  • DOI: https://doi.org/10.1007/BF00955358

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