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Relative stability of 1-substituted perfluoromethallyl cations according to19F NMR data

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

The relative stability of perfluoromethallyl cations substituted at the 1 position decreases, depending on the substituent, in the following series: OMe > I > Br > Cl > F.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    M. V. Galakhov, G. G. Belen'kii, V. A. Petrov, É. I. Fedin & V. I. Bakhmutov

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  1. M. V. Galakhov
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  2. G. G. Belen'kii
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  3. V. A. Petrov
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  4. É. I. Fedin
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  5. V. I. Bakhmutov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1054–1057, May, 1986.

The authors wish to express their gratitude to Yu. V. Zeifman and S. A. Postovoi for providing the samples of 1-bromo- and 1-iodoperfluoroisobutylenes.

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Galakhov, M.V., Belen'kii, G.G., Petrov, V.A. et al. Relative stability of 1-substituted perfluoromethallyl cations according to19F NMR data. Russ Chem Bull 35, 957–959 (1986). https://doi.org/10.1007/BF00955357

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  • DOI: https://doi.org/10.1007/BF00955357

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