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Investigation of the separation of charges in molecules of bisarene π complexes of metals by analyzing the intensities in infrared spectra

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The effective charges on the atoms in the bisbenzene complexes of vanadium, chromium, and molybdenum have been calculated in the framework of the first approximation of the model of effective charges on the basis of experimental data on the integrated intensities of bands in their IR spectra.

  2. 2.

    The effective charges on the metal atoms in the bisarene complexes studied are somewhat higher than those in the corresponding biscyclopentadienyl compounds and lie in the range from 0.5e to 0.9e.

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Literature cited

  1. S. Kh. Samvelyan, V. T. Aleksanyan, and B. V. Lokshin, J. Mol. Spectres.,48, 47, 566 (1973).

    Google Scholar 

  2. V. T. Aleksanyan and I. I. Grinval'd (Greenwald), J. Mol. Struct.,90, 35 (1982).

    Google Scholar 

  3. D. A. Clemente, M. C. Biagini, B. Ress, and W. A. Herrmann, Inorg. Chem.,21, 3741 (1982).

    Google Scholar 

  4. N. A. Ogorodnikova and A. A. Koridze, Polyhedron,2, 941 (1983).

    Google Scholar 

  5. I. A. Garbuzova, O. G. Garkusha, B. V. Lokshin, G. K. Borisov, and T. S. Morozova, J. Organometal. Chem.,279, 327 (1985).

    Google Scholar 

  6. H. P. Fritz, Adv. Organomet. Chem.,1, 239 (1964).

    Google Scholar 

  7. L. Schafer, J. F. Soutern, and S. Cyvin, Spectrochim. Acta,27A, 1083 (1971).

    Google Scholar 

  8. S. J. Cyvin, B. N. Cyvin, J. Brunvoll, and L. Schafer, Acta Chim. Scand.,24, 3420 (1970).

    Google Scholar 

  9. S. J. Cyvin and J. Brunvoll, J. Chem. Phys.,54, 1517 (1971).

    Google Scholar 

  10. J. Brunvoll, S. J. Cyvin, and L. Schafer, J. Organomet. Chem.,27, 69 (1971).

    Google Scholar 

  11. V. T. Aleksanyan, N. N. Vyshinskii, I. I. Grinval'd, and T. I. Arsen'eva, Izv. Akad. Nauk SSSR, Ser. Khim., 303 (1981).

  12. W. E. Silverthorn, Adv. Organomet. Chem.,13, 47 (1975).

    Google Scholar 

  13. P. C. Painter and J. L. Koenig, Spectrochim. Acta, 33A, 1019 (1977).

    Google Scholar 

  14. G. R. Durig (ed.), Vibrational Spectra and Structure, Elsevier, New York (1982), p. 107.

    Google Scholar 

  15. J. A. Connor, L. M. R. Derrick, and I. N. Hillier, J. Chem. Soc., Faraday Trans. II, 941 (1974).

  16. N. M. Klimenko, Quantum-Mechanical Calculations of Complex Compounds of Transition Metals [in Russian], VINITI, Moscow (1978).

    Google Scholar 

  17. A. N. Nesmeyanov and K. A. Kocheshkov (eds.), Methods of Organometallic Chemistry [in Russian], Nauka, Moscow (1975).

    Google Scholar 

  18. V. T. Aleksanyan, T. I. Arsen'eva, N. N. Vyshinskii, I. I. Grinval'd, and A. S. Smirnov, Izv. Akad. Nauk SSSR, Ser. Khim., 299 (1981).

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organometallic Compounds, Academy of Sciences of the USSR, Moscow

    I. I. Grinval'd, B. V. Lokshin & N. K. Rudnevskii

Authors
  1. I. I. Grinval'd
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  2. B. V. Lokshin
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  3. N. K. Rudnevskii
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1047–1054, May, 1986.

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Grinval'd, I.I., Lokshin, B.V. & Rudnevskii, N.K. Investigation of the separation of charges in molecules of bisarene π complexes of metals by analyzing the intensities in infrared spectra. Russ Chem Bull 35, 950–956 (1986). https://doi.org/10.1007/BF00955356

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  • DOI: https://doi.org/10.1007/BF00955356

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