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C,N and C,S transfers in exchange equilibria involving 4-fluorophenylacetylene, benzenesulfonanilide, and thiophenol and their organometallic derivatives

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A19F-{1H} NMR study was carried out on the effect of the nature of the key element of HX acids [X=SPh and N(SO2Ph)Ph] on the position of the equilibrium of exchange reactions in solutions of mixtures containing the HX acid, 4-fluorophenylacetylene, and/or their organo-metallic derivatives in toluene and DMSO.

  2. 2.

    The ratio of the dissociation constants of the Q-N bonds to the dissociation constants of the Q-C bonds increases in the series: Ph3Pb > H > Ph3Sn > cycle C6H11Hg > PhHg.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    A. S. Peregudov, V. F. Ivanov & D. N. Kravtsov

Authors
  1. A. S. Peregudov
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  2. V. F. Ivanov
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  3. D. N. Kravtsov
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1041–1047, May, 1986.

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Peregudov, A.S., Ivanov, V.F. & Kravtsov, D.N. C,N and C,S transfers in exchange equilibria involving 4-fluorophenylacetylene, benzenesulfonanilide, and thiophenol and their organometallic derivatives. Russ Chem Bull 35, 945–950 (1986). https://doi.org/10.1007/BF00955355

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  • DOI: https://doi.org/10.1007/BF00955355

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