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Calculation of the rate constants of heterogeneous electron-transfer reactions with the participation of metal complexes

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

Numerical estimates of the electronic transition-matrix elements for a number of heterogeneous electron-transfer reactions have been obtained. The main kinetic parameters of homo-geneous and heterogeneous redox systems formed by complexes of transition metals with water and ammonia as ligands have been compared.

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Authors and Affiliations

  1. A. N. Frumkin Institute of Electrochemistry, Academy of Sciences of the USSR, Moscow

    É. D. German & A. M. Kuznetsov

Authors
  1. É. D. German
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  2. A. M. Kuznetsov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1016–1020, May, 1986.

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German, É.D., Kuznetsov, A.M. Calculation of the rate constants of heterogeneous electron-transfer reactions with the participation of metal complexes. Russ Chem Bull 35, 922–925 (1986). https://doi.org/10.1007/BF00955350

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  • DOI: https://doi.org/10.1007/BF00955350

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