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Effect of composition of 12-series heteropoly compounds on their generation of hydrogen from acid aqueous alcoholic solutions

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Investigation of 17 different heteropoly compounds of tungsten and molybdenum confirms that the capability for spontaneous evolution of hydrogen from water is a quite general property of the reduced forms of such compounds in acidic aqueous and aqueous alcoholic solution.

  2. 2.

    The reduced formed of mixed-ligand HPAs and HPAs with various central atoms evolve hydrogen at similar rates (within the limits of an order of magnitude). At the same time, the degree of reduction required for spontaneous hydrogen evolution depends substantially on the nature of the HPA.

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Authors and Affiliations

  1. Institute of Catalysis, Siberian Branch of the Academy of Sciences, Novosibirsk

    S. S. Saidkhanov, E. N. Savinov, K. I. Matveev, L. G. Maksimova, V. N. Parmon & K. I. Zamaraev

  2. Institute of Natural Sciences, Buryat Affiliate, Siberian Branch of the Academy of Sciences of the USSR, Ulan-Ude

    S. S. Saidkhanov, E. N. Savinov, K. I. Matveev, L. G. Maksimova, V. N. Parmon & K. I. Zamaraev

Authors
  1. S. S. Saidkhanov
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  2. E. N. Savinov
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  3. K. I. Matveev
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  4. L. G. Maksimova
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  5. V. N. Parmon
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  6. K. I. Zamaraev
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1006–1012, May, 1986.

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Saidkhanov, S.S., Savinov, E.N., Matveev, K.I. et al. Effect of composition of 12-series heteropoly compounds on their generation of hydrogen from acid aqueous alcoholic solutions. Russ Chem Bull 35, 913–918 (1986). https://doi.org/10.1007/BF00955348

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  • DOI: https://doi.org/10.1007/BF00955348

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