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Trisacetylacetonates of cobalt(II) and nickel(II) with the tetrabutylammonium cation at the outer sphere

  • Inorganic Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

The trisacetylacetonates of cobalt and nickel with the tetrabutylammonium cation in the outer sphere have been synthesized by the interaction of tetrabutylammonium hydroxide, acetylacetone, and the dihydrates of cobalt and nickel bisacetylacetonates. The nickel complex is thermally more stable than the cobalt complex. When heated in vacuum, both complexes decompose into tetrabutylammonium acetylacetonate and anhydrous acetylacetonates of cobalt(II) and nickel(II).

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Authors and Affiliations

  1. M. V. Lomonosov Moscow State University, USSR

    A. Yu. Steblyanko, A. N. Grigor'ev, L. I. Martynenko & V. I. Spitsyn

Authors
  1. A. Yu. Steblyanko
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  2. A. N. Grigor'ev
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  3. L. I. Martynenko
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  4. V. I. Spitsyn
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 975–978, May, 1986.

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Steblyanko, A.Y., Grigor'ev, A.N., Martynenko, L.I. et al. Trisacetylacetonates of cobalt(II) and nickel(II) with the tetrabutylammonium cation at the outer sphere. Russ Chem Bull 35, 884–887 (1986). https://doi.org/10.1007/BF00955341

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  • DOI: https://doi.org/10.1007/BF00955341

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