Radical reaction of ethyl orthoacetate with 3,3,3-trifluoropropene
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The reaction of 3,3,3-trifluoropropene with ethyl orthoacetate leads to the formation of an acetate CH3C(O)OCH(CH3)CH2CH2CF3 and a ketone CH3C(O)CH2CH(CF3)CH2CH2CF3. A reaction mechanism is proposed which involves rearrangement of the radicals CR3C(OC2H5)2OCH(CH3) (CH2CHCF3) n . with 1,7- and 1,5-migration of an H atom and stabilization by fragmentation.
KeywordsAcetate Ethyl Ketone Reaction Mechanism Radical Reaction
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