Molecular structure of N,N′-bis(phenylsulfonyl)-p-phenylenediamine

  • V. N. Nesterov
  • V. E. Shklover
  • Yu. T. Struchkov
  • V. A. Sergeev
  • V. I. Nedel'kin
  • S. A. Arnautov
Physical Chemistry
  • 25 Downloads

Conclusions

  1. 1.

    As a result of x-ray crystallographic investigation it was established that the molecule of N,N'-bis(phenylsulfonyl)-p-phenylenediamine has a nonpolar twisted structure. (The dihedral angle between the central and terminal benzene rings amounts to 68.0°.)

     
  2. 2.

    The nonplanar structure and the absence of shortened S-C(Ph), S-N, and N-C(Ph) distances rules out the possibility of π conjugation of the benzene rings through the sulfonamide groups.

     

Keywords

Sulfonamide Benzene Molecular Structure Benzene Ring Dihedral Angle 

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Copyright information

© Plenum Publishing Corporation 1987

Authors and Affiliations

  • V. N. Nesterov
    • 1
  • V. E. Shklover
    • 1
  • Yu. T. Struchkov
    • 1
  • V. A. Sergeev
    • 1
  • V. I. Nedel'kin
    • 1
  • S. A. Arnautov
    • 1
  1. 1.A. N. Nesmeyanov Institute of Heteroorganic CompoundsAcademy of Sciences of the USSRMoscow

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