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1H and13C NMR spectra of certain derivatives of silacyclopentanes, and their isomers

  • A. A. Panasenko
  • L. V. Spirikhin
  • I. A. Gailyunas
  • G. A. Tolstikov
Physical Chemistry

Conclusions

  1. 1.

    A study has been made of the1H and13C NMR spectra of six 1,1,3,4-substituted silacyclopentanes, and the spectral parameters have been obtained.

     
  2. 2.

    For the substituted silacyclopentanes, the same as for 3,4-substituted sulfolanes, the isomerism of the compounds can be established on the basis of the difference between chemical shifts of the geminal protons at C2 and C5 in the1H NMR spectra, and also according to the chemical shifts and direct carbon-proton constants of the13C atoms bonded to a substituent in the13C NMR spectra.

     

Keywords

Chemical Shift Spectral Parameter Sulfolanes Geminal Proton Silacyclopentanes 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

  1. 1.
    L. V. Spirikhin, R. A. Sadykov, B. V. Flekhter, N. N. Novitskaya, A. A. Panasenko, and G. A. Tolstikov, Izv. Akad. Nauk SSSR, Ser. Khim., 1029 (1980).Google Scholar
  2. 2.
    R. V. Kunakova, F. V. Sharipova, G. A. Tolstikov, L. M. Zelenova, A. A. Panasenko, L. V. Spirikhin, and U. M. Dzhemilev, Izv. Akad. Nauk SSSR, Ser. Khim., 1833 (1980).Google Scholar
  3. 3.
    A. A. Panasenko, L. V. Spirikhin, V. S. Sultanova, R. A. Sadykov, and G. A. Tolstikov, Izv. Akad. Nauk SSSR, Ser. Khim., 2723 (1983).Google Scholar
  4. 4.
    J. W. Cooper, Spectroscopic Techniques for Organic Chemists, New York (1980).Google Scholar
  5. 5.
    M. Anteunis and D. Danneels, Org. Magn. Reson.,7, 345 (1975).Google Scholar

Copyright information

© Plenum Publishing Corporation 1987

Authors and Affiliations

  • A. A. Panasenko
    • 1
  • L. V. Spirikhin
    • 1
  • I. A. Gailyunas
    • 1
  • G. A. Tolstikov
    • 1
  1. 1.Institute of ChemistryBashkir Branch of the Academy of Sciences of the USSRUfa

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