19F NMR spectrum of perfluoropentadienyl cation, and calculation of its geometry by the LCAO MO method in the indo approximation

  • M. V. Galakhov
  • Yu. A. Borisov
  • V. A. Petrov
  • G. G. Belen'kii
  • L. S. German
  • V. I. Bakhmutov
Physical Chemistry
  • 20 Downloads

Conclusions

  1. 1.

    For the first time, the existence of the perfluoropentadienyl cation has been established by means of19F NMR.

     
  2. 2.

    The LCAO MO method in the INDO approximation has been used to calculate the structure of the perfluoropentadienyl cation, which, according to the NMR data, exists in the form of the (s-trans, s-trans) species.

     

Keywords

INDO Approximation 

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Copyright information

© Plenum Publishing Corporation 1987

Authors and Affiliations

  • M. V. Galakhov
    • 1
  • Yu. A. Borisov
    • 1
  • V. A. Petrov
    • 1
  • G. G. Belen'kii
    • 1
  • L. S. German
    • 1
  • V. I. Bakhmutov
    • 1
  1. 1.A. N. Nesmeyanov Institute of Heteroorganic CompoundsAcademy of Sciences of the USSRMoscow

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