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Complexing of some rare-earth metal chlorides with aluminum chloride and use of these complexes for the polymerization of dienes

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

The anhydrous neodymium, praseodymium, and yttrium chlorides react with AlCl5 to give LnCl3·4AlCl3 complexes that are soluble in aromatic hydrocarbons. The lanthanide concentration in solution increases by one order of magnitude if an organoaluminum compound is added to the reaction mixture after the completion of complex formation between the lanthanide and aluminum chlorides.

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Authors and Affiliations

  1. A. V. Topchiev Institute of Petrochemical Synthesis, Academy of Sciences of the USSR, Moscow

    K. G. Miesserov, E. I. Tinyakova & B. A. Dolgoplosk

Authors
  1. K. G. Miesserov
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  2. E. I. Tinyakova
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  3. B. A. Dolgoplosk
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Additional information

Translated from Izvestlya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2828–2829, December, 1983.

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Miesserov, K.G., Tinyakova, E.I. & Dolgoplosk, B.A. Complexing of some rare-earth metal chlorides with aluminum chloride and use of these complexes for the polymerization of dienes. Russ Chem Bull 32, 2540–2541 (1983). https://doi.org/10.1007/BF00954490

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  • DOI: https://doi.org/10.1007/BF00954490

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