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Cyanomethyl derivatives of gold

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Triphenylphosphine complexes of cyanomethylgold and dichlorocyanomethylgold have been synthesized.

  2. 2.

    The chemical properties of aurated acetonitrile were typical for σ organogold compounds but aurated dichloroacetonitrile recalled the chemical behavior of complex gold halides

  3. 3.

    The gold atom in the molecule of dichlorocyanomethyl (triphenylphosphine) gold has linear coordination, the bond lengths and angles were typical for organic complexes of univalent gold.

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Literature cited

  1. K. I. Grandberg, Usp. Khim.,1, Pt. 3, 438 (1982).

    Google Scholar 

  2. E. I. Smyslova, E. G. Perevalova, V. P. Dyadchenko, K. I. Grandberg, Yu. L. Slovokhotov, and Yu. T. Struchkov, J. Organomet. Chem.,215, 269 (1981).

    Google Scholar 

  3. L. A. Kazitsina, I. F. Lutsenko, G. A. Rudenko, and A. N. Nesmeyanov, Dokl. Akad. Nauk SSSR,127, 115 (1959).

    Google Scholar 

  4. V. P. Dyadchenko, Vestn. Mosk. Unta,17, No. 3, 358 (1976).

    Google Scholar 

  5. L. Lochmann and D. Lim, J. Organomet. Chem.,50, 9 (1973).

    Google Scholar 

  6. R. A. Michelin, M. Napoli, and R. Ros, J. Organomet. Chem.,175, 239 (1979).

    Google Scholar 

  7. H. Schmidbaur and A. Shiotani, Chem. Ber.,104, 2821 (1971).

    Google Scholar 

  8. A. N. Nesmeyanov, E. G. Perevalova, E. I. Smyslova, V. P. Dyadchenko, and K. I. Grandberg, Izv. Akad. Nauk SSSR, Ser. Khim., 2610 (1977).

  9. P. D. Gavens, J. J. Guy, M. J. Mays, and G. M. Sheldrick, Acta Crystallogr.,B33, 137 (1977).

    Google Scholar 

  10. R. W. Baker and P. J. Pauling, J. Chem. Soc. Dalton Trans., 2264 (1972).

  11. L. V. Vilkov, V. S. Mastryukov, and N. I. Sadova, Determination of the Geometric State of Free Molecules [in Russian], Khimiya, Leningrad (1978), p. 118.

    Google Scholar 

  12. G. Matsubayashi, Y. Kondo, T. Tanaka, S. Nishigaki, and K. Nakatsu, Chem. Lett., 375 (1979).

  13. R. G. Gerr, M. Yu. Antipin, N. G. Furmanova, and Yu. T. Struchkov, Krystallografiya,24, 951 (1979).

    Google Scholar 

  14. W. C. Hamilton, Acta Crystallogr.,18, 502 (1965).

    Google Scholar 

  15. E. M. Kaiser and C. R. Hauser, J. Org. Chem.,33, 3402 (1968).

    Google Scholar 

  16. K. I. Grandberg, T. V. Baukova, É. G. Perevalova, and A. N. Nesmeyanov, Dokl. Akad. Nauk SSSR,206, 1355 (1972).

    Google Scholar 

  17. L. H. Jones and R. A. Penneman, J. Chem. Phys.,22, 965 (1954).

    Google Scholar 

  18. A. N. Nesmeyanov, É. G. Perevalova, D. A. Lemenovskii, A. N. Kosina, and K. I. Grandberg, Izv. Akad. Nauk SSSR, Ser. Khim., 2030 (1969).

  19. É. G. Perevalova, D. A. Lemonovskii, K. I. Grandberg, and A. N. Nesmeyanov, Dokl. Akad. Nauk SSSR,202, 93 (1972).

    Google Scholar 

  20. L. H. Jones, J. Chem. Phys.,43, 594 (1965).

    Google Scholar 

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    É. G. Perevalova, Yu. T. Struchkov, V. P. Dyadchenko, E. I. Smyslova, Yu. L. Slovokhotov & K. I. Grandberg

  2. M. V. Lomonosov Moscow State University, USSR

    É. G. Perevalova, Yu. T. Struchkov, V. P. Dyadchenko, E. I. Smyslova, Yu. L. Slovokhotov & K. I. Grandberg

Authors
  1. É. G. Perevalova
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  2. Yu. T. Struchkov
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  3. V. P. Dyadchenko
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  4. E. I. Smyslova
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  5. Yu. L. Slovokhotov
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  6. K. I. Grandberg
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2818–2824, December, 1983.

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Perevalova, É.G., Struchkov, Y.T., Dyadchenko, V.P. et al. Cyanomethyl derivatives of gold. Russ Chem Bull 32, 2529–2536 (1983). https://doi.org/10.1007/BF00954488

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  • DOI: https://doi.org/10.1007/BF00954488

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