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Comparative study of electrochemical reductions of 3-formyl-[3]-ferrocenophane and acetylferrocene

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Electrolytic reduction of 3-formyl-[3]-ferrocenophane and acetylferrocene proceeds through the anion radical formation step.

  2. 2.

    The influence of the structure on the behavior of the anion radicals being formed manifests itself only in nonaqueous solutions, in which the anion radical of acetylferrocene breaks down with rupture of the bond between the metal and the cyclopentadiene ring, whereas the anion radicals of [3]-ferrocenophanes retain the ferrocene structure, the break-down of which is prevented by the three-carbon bridge.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    M. G. Peterleitner, L. I. Denisovich, A. Z. Kreindlin, S. S. Fadeeva, M. I. Rybinskaya & D. B. Zagorevskii

Authors
  1. M. G. Peterleitner
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  2. L. I. Denisovich
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  3. A. Z. Kreindlin
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  4. S. S. Fadeeva
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  5. M. I. Rybinskaya
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  6. D. B. Zagorevskii
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2814–2818, December, 1983.

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Peterleitner, M.G., Denisovich, L.I., Kreindlin, A.Z. et al. Comparative study of electrochemical reductions of 3-formyl-[3]-ferrocenophane and acetylferrocene. Russ Chem Bull 32, 2526–2529 (1983). https://doi.org/10.1007/BF00954487

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  • DOI: https://doi.org/10.1007/BF00954487

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