Conclusions
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1.
Higher internal perfluoroolefins are readily reduced by catalytic hydrogenation and treatment with complex metal hydrides.
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2.
The hydrogenation of fluoroolefins on palladium catalysts proceeds with rigorous steric specificity.
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Literature cited
A. L. Henne and S. Kaye, J. Am. Chem. Soc.,72, 3369 (1950).
R. N. Hazeldine, J. Chem. Soc., 2504 (1952).
I. L. Knunyants, E. I. Mysov, and M. P. Krasuskaya, Izv. Akad. Nauk SSSR, Ser. Khim., 906 (1958).
L. L. Knunyants, E. I. Mysov, and M. P. Krasuskaya, Izv. Akad. Nauk SSSR, Ser. Khim., 1412 (1960).
D. J. Burton and R. L. Johnson, J. Am. Chem. Soc.,86, 5361 (1964).
D. J. Burton, R. L. Johnson, and R. T. Bogan, Canad. J. Chem.,44, 635 (1966).
M. H. Kaufman, J. D. Brann, and J. Shdo, J. Org. Chem.,32, 2749 (1967).
F. J. Mettile and D. J. Burton, Fluor. Chem. Rev.,1, 315 (1967).
V. A. Petrov, G. G. Belen'kii, L. S. German, and E. I. Mysov, Izv. Akad. Nauk SSSR, Ser. Khim., 2098 (1981).
V. V. Petrov, G. G. Belen'kii, and L. S. German, Izv. Akad. Nauk SSSR, Ser. Khim., 1920 (1981).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2775–2781, December, 1983.
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Snegirev, V.F., Makarov, K.N., Zabolotskikh, V.F. et al. Catalytic and hydride reduction of hexafluoropropylene dimers. Russ Chem Bull 32, 2489–2494 (1983). https://doi.org/10.1007/BF00954480
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DOI: https://doi.org/10.1007/BF00954480