Crystal structure of peroxydisuccinic acid

  • S. V. Lindeman
  • V. E. Shklover
  • Yu. T. Struchkov
  • E. K. Starostin
  • G. I. Nikishin
Physical Chemistry
  • 30 Downloads

Conclusions

  1. 1.

    The crystal structure and molecular structure of peroxydisuccinic acid have been determined.

     
  2. 2.

    Similarity has been found in most of the stereochemical parameters of peroxydisuccinic, succinic, and fumaric acids, and approximate isomorphism has been shown for the per-oxydisuccinic acid and the β-form of succinic acid.

     
  3. 3.

    On the basis of an analysis of the crystal and molecular structures of these compounds, a hypothesis has been advanced as to the stereochemical factors favoring inclusion of the peroxydisuccinic acid in the matrix of succinic or fumaric acid during cocrystallization, and also the factors destabilizing the peroxide group in these matrices and favoring its homolytic decomposition.

     

Keywords

Peroxide Crystal Structure Molecular Structure Succinic Acid Fumaric Acid 

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Copyright information

© Plenum Publishing Corporation 1984

Authors and Affiliations

  • S. V. Lindeman
    • 1
    • 2
  • V. E. Shklover
    • 1
    • 2
  • Yu. T. Struchkov
    • 1
    • 2
  • E. K. Starostin
    • 1
    • 2
  • G. I. Nikishin
    • 1
    • 2
  1. 1.A. N. Nesmeyanov Institute of Heteroorganic CompoundsAcademy of Sciences of the USSRMoscow
  2. 2.N. D. Zelinskii Institute of Organic ChemistryAcademy of Sciences of the USSRMoscow

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