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Study of the direct carbon-proton constants of the spin-spin interaction in sulfolane derivatives

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

The increments of the chemical shift and spin-spin interaction constants for a series of substituents were determined based on a study of the13C NMR spectra of sulfolane and its 3- and 3,4-substituted derivatives. The values of the direct CSSI at C3 and C4 for cis-3,4-disubstituted sulfolanes with the same substituents are criteria which permit determining the steric orientation of the substituents and the isomerism of sulfolanes.

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Authors and Affiliations

  1. Institute of Chemistry, Bashkir Branch, Academy of Sciences of the USSR, Ufa

    A. A. Panasenko, L. V. Spirikhin, V. S. Sultanova, R. A. Sadykov & G. A. Tolstikov

Authors
  1. A. A. Panasenko
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  2. L. V. Spirikhin
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  3. V. S. Sultanova
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  4. R. A. Sadykov
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  5. G. A. Tolstikov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2723–2727, December, 1983.

We would like to thank N. N. Novitskaya and B. V. Flekhter for supplying the sulfolane derivatives for the study.

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Panasenko, A.A., Spirikhin, L.V., Sultanova, V.S. et al. Study of the direct carbon-proton constants of the spin-spin interaction in sulfolane derivatives. Russ Chem Bull 32, 2442–2445 (1983). https://doi.org/10.1007/BF00954471

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  • DOI: https://doi.org/10.1007/BF00954471

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