Chemiluminescence in the oxidation of unsaturated organic compounds in solution

  • V. A. Belyakov
  • R. F. Vasil'ev
  • G. F. Fedorova
Physical Chemistry


In the oxidation of unsaturated compounds, certain processes that form various electronexcited products make various contributions to chemiluminescence (CL). In pure olefins there is no CL; in actual samples CL is due to traces of peroxides. In the initiated olefin oxidation the low CL intensity is due to the excitation yield and the low emission yield of the primary emitter, an alkenone. Activator-intensified CL can be used to determine the kinetics of the radical-chain oxidation of olefins.


Oxidation Peroxide Organic Compound Olefin Oxidation Actual Sample 
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Copyright information

© Plenum Publishing Corporation 1984

Authors and Affiliations

  • V. A. Belyakov
    • 1
  • R. F. Vasil'ev
    • 1
  • G. F. Fedorova
    • 1
  1. 1.Institute of Chemical PhysicsAcademy of Sciences of the USSRMoscow

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