Chemiluminescence in the oxidation of unsaturated organic compounds in solution

  • V. A. Belyakov
  • R. F. Vasil'ev
  • G. F. Fedorova
Physical Chemistry
  • 30 Downloads

Conclusions

In the oxidation of unsaturated compounds, certain processes that form various electronexcited products make various contributions to chemiluminescence (CL). In pure olefins there is no CL; in actual samples CL is due to traces of peroxides. In the initiated olefin oxidation the low CL intensity is due to the excitation yield and the low emission yield of the primary emitter, an alkenone. Activator-intensified CL can be used to determine the kinetics of the radical-chain oxidation of olefins.

Keywords

Oxidation Peroxide Organic Compound Olefin Oxidation Actual Sample 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Literature cited

  1. 1.
    R. F. Vasil'ev, Usp. Khim., 39, 1130 (1970).Google Scholar
  2. 2.
    V. A. Belyakov and R. F. Vasil'ev, Molecular Photonics [in Russian], Nauka, Leningrad (1970), p. 70.Google Scholar
  3. 3.
    V. A. Belyakov, R. F. Vasil'ev, and G. F. Fedorova, Izv. Akad. Nauk SSSR Ser. Fiz.,42, 613 (1978).Google Scholar
  4. 4.
    V. A. Belyakov, R. F. Vasil'ev, and G. F. Fedorova, Khim. Vys. Energ.,12, 247 (1978).Google Scholar
  5. 5.
    V. A. Belyako, T. V. Filippova, S. Yu. Zasedatelev, and E. A. Blyumberg, Izv. Akad. Nauk SSSR, Ser. Khim., 1485 (1979).Google Scholar
  6. 6.
    L. M. Pisarenko, A. B. Gagarina, and N. M. Émanuel', Dokl. Akad. Nauk SSSR,221, 640 (1975).Google Scholar
  7. 7.
    N. M. Émanuel', E. T. Denisov, and Z. K. Maizus, Chain Oxidations of Hydrocarbons in the Liquid Phase [in Russian], Nauka, Moscow (1965), p. 120.Google Scholar
  8. 8.
    V. A. Belyakov, R. F. Vasil'ev, and G. F. Fedorova, Dokl. Akad. Nauk SSSR,239, 344 (1978).Google Scholar
  9. 9.
    P. DeMayo, A. A. Nicholson, and M. F. Tchir, Can. J. Chem.,48, 225 (1970).Google Scholar
  10. 10.
    S. MacGlynn, T. Adzumi, and M. Kinoshita, Molecular Spectroscopy of the Triplet State [Russian translation], Mir, Moscow (1972), p. 268.Google Scholar
  11. 11.
    W. Pritzkow, R. Radeglia, and W. Schmidt-Renner, J. Prakt. Chem.,321, 813 (1979).Google Scholar
  12. 12.
    D. Van Sickle, F. Mayo, and R. Arluck, J. Am. Chem. Soc.,87, 4824 (1965).Google Scholar

Copyright information

© Plenum Publishing Corporation 1984

Authors and Affiliations

  • V. A. Belyakov
    • 1
  • R. F. Vasil'ev
    • 1
  • G. F. Fedorova
    • 1
  1. 1.Institute of Chemical PhysicsAcademy of Sciences of the USSRMoscow

Personalised recommendations