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Liquid-phase codimerization of ethylene with propylene on nickel carbonyl triphenylphosphine complex anchored on surface of aluminum oxide

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The catalytic system Ni(CO)x(PPh3)y/A12O3-Et3Al2Cl3 (x + y=4) is active at 40°C in copolymerization of ethylene with propylene over a broad range of monomer concentrations.

  2. 2.

    The molecular weight distribution and structural composition of the products depends on the ratio γo=[C3H6]/[C2H4]o. The maximum yield of C5 olefins is 45% with γo=7–32.

  3. 3.

    Under conditions of codimerization, ethylene accelerates the dimerization of propylene quite substantially.

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Literature cited

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    D. B. Furman, N. V. Volchkov, L. A. Makhlis, S. A. Chernov, V. É. Vasserberg & O. V. Bragin

Authors
  1. D. B. Furman
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  2. N. V. Volchkov
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  3. L. A. Makhlis
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  4. S. A. Chernov
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  5. V. É. Vasserberg
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  6. O. V. Bragin
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2693–2696, December, 1983.

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Furman, D.B., Volchkov, N.V., Makhlis, L.A. et al. Liquid-phase codimerization of ethylene with propylene on nickel carbonyl triphenylphosphine complex anchored on surface of aluminum oxide. Russ Chem Bull 32, 2414–2416 (1983). https://doi.org/10.1007/BF00954466

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  • DOI: https://doi.org/10.1007/BF00954466

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