Palladium on poly{benzo[bis(Benzimidazolo)phenanthroline]dione} as a catalyst for the hydrogenation of unsaturated compounds

  • A. A. Belyi
  • L. G. Chigladze
  • A. L. Rusanov
  • G. T. Gurgenidze
  • M. E. Vol'pin
Physical Chemistry

Conclusions

  1. 1.

    Palladium chloride supported on poly{benzo[bis(benzimidazolo)phenanthroline]dione (PBI) is reduced by hydrogen to PBI·Pd, which is an active catalyst of the hydrogenation of unsaturated compounds and also the isomerization of olefins and allyl alcohol.

     
  2. 2.

    The PBI·Pd catalyzes the disproportionation of cyclohexadiene to benzene and cyclohexene.

     

Keywords

Hydrogenation Alcohol Chloride Benzene Active Catalyst 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Literature cited

  1. 1.
    A. L. Rusanov, S. N. Leont'eva, and Ts. G. Preshashvili, Usp. Khim.,46, 151 (1977).Google Scholar
  2. 2.
    O. R. Hughes, U.S. Pat. 4,077,906 (1978).Google Scholar
  3. 3.
    R. D. Taylor, U. S. Pat. 3,985,679 (1976).Google Scholar
  4. 4.
    V. V. Korshak, A. L. Rusanov, A. M. Berlin, S. Kh. Fidler, and F. I. Adyrkhaeva, Vysokomol. Soedin. A,21, 68 (1979).Google Scholar
  5. 5.
    I. B. Dobroserdova, V. Yu. Fishbein, A. I. Leonova, and I. V. Gostunskaya, Vestn. Mosk. Univ., Ser. Khim.,22, 192 (1981).Google Scholar
  6. 6.
    L. Kh. Freidlin and E. F. Litvin, in: Problems in Kinetics and Catalysis. XI. Scientific Principles of Catalyst Selection for Heterogeneous Catalytic Reactions [in Russian], Nauka, Moscow (1966), p. 162.Google Scholar
  7. 7.
    M. Orchin, in: Catalysis. Stereochemistry and Mechanisms of Organic Reactions [Russian translation], Mir, Moscow (1968), p. 7.Google Scholar
  8. 8.
    S. Zigel', in: Catalysis. Stereochemistry and Mechanisms of Organic Reactions [Russian translation], Mir, Moscow (1968), p. 127.Google Scholar
  9. 9.
    N. D. Zelinskii and G. S. Pavlov, Chem. Ber.,66, 1420 (1933).Google Scholar
  10. 10.
    V. N. Perchenko, I. S. Mirskova, and N. S. Nametkin, Neftekhimiya,20, 518 (1980).Google Scholar

Copyright information

© Plenum Publishing Corporation 1984

Authors and Affiliations

  • A. A. Belyi
    • 1
  • L. G. Chigladze
    • 1
  • A. L. Rusanov
    • 1
  • G. T. Gurgenidze
    • 1
  • M. E. Vol'pin
    • 1
  1. 1.A. N. Nesmeyanov Institute of Heteroorganic CompoundsAcademy of Sciences of the USSRMoscow

Personalised recommendations