Kinetics of hydrogen sulfide oxidation by polyanions in aqueous solution

  • I. V. Kozhevnikov
  • O. A. Kholdeeva
Inorganic Chemistry


The kinetics of hydrogen sulfide oxidation in aqueous solution have been studied in the presence of 12-molybdovanadophosphate heteropolyanions at pH 3.0. The reaction rate obeys the Michaelis equation. Under these conditions the actual oxidant is the isopolyanion that is present in solution in equilibrium with the heteropolyanion.


Oxidation Hydrogen Aqueous Solution Sulfide Hydrogen Sulfide 
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Copyright information

© Plenum Publishing Corporation 1984

Authors and Affiliations

  • I. V. Kozhevnikov
    • 1
  • O. A. Kholdeeva
    • 1
  1. 1.Institute of Catalysis, Siberian BranchAcademy of Sciences of the USSRNovosibirsk

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