Conclusions
The desulfurization of tetrahydrothiophene using triiron dodecacarbonyl was run for the first time. The desulfurization proceeds via the step of forming sulfur carbonyl clusters.
Literature cited
F. A. Cotton and J. M. Troup, J. Am. Chem. Soc.,96, 5070 (1974).
F. A. Cotton, J. R. Kolb, and B. R. Stults, Inorg. Chim. Acta,15, 239 (1975).
A. Shaver, P. J. Fitzpatrick, K. Stelion, and I. S. Butler, J. Am. Chem. Soc.,101, 1313 (1979).
K. Takahashi, M. Iwanami, A. Tsai, P. W. Chang, R. L. Harlow, L. E. Harris, J. E. McCaskie, C. E. Phluger, and D. C. Dittmer, J. Am. Chem. Soc.,95, 6113 (1973).
H. D. Kaesz, R. B. King, T. A. Manuel, L. D. Nickols, and F. G. A. Stone, J. Am. Chem. Soc.,82, 4749 (1960).
P. Hübener and E. Weiss, J. Organomet. Chem.,129, 105 (1977).
W. Strohmeier, J. F. Guttenberger, and G. Popp, Chem. Ber.,98_, 2248 (1965).
N. S. Nametkin and V. D. Tyurin, Preprints Division of Petroleum Chemistry, Texas: Am. Chem. Soc. Houston (1980), Vol. 25, No. 2, p. 229.
N. S. Nametkin, V. D. Tyurin, G. G. Aleksandrov, O. V. Kuz'min, A. I. Nekhaev, V. G. Andrianov, M. Mavlonov, and Yu. T. Stryuchkov, Izv. Akad. Nauk SSSR, Ser. Khim. 1353 (1979).
N. S. Nametkin, V. D. Tyurin, and M. A. Kukina, J. Organomet. Chem.,149, 355 (1978).
USSR Patent 561,727, Byull. Izobret., No. 22 (1977); Belgium Patent 829,175 (1975); British Patent 1,465,254 (1977); U. S. Patent No. 4,132,631 (1979); German Patent 2,521,897 (1980).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1667–1669, July, 1983.
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Nametkin, N.S., Tyurin, V.D. & Podol'skaya, I.P. Desulfurization of tetrahydrothiophene by triiron dodecacarbonyl. Russ Chem Bull 32, 1515–1517 (1983). https://doi.org/10.1007/BF00954374
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DOI: https://doi.org/10.1007/BF00954374