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Derivatives of N-oxyl- and N-oxopiperidylacetic acids

  • V. D. Sen'
  • E. V. Kapustina
  • V. A. Golubev
Organic Chemistry

Conclusions

  1. 1.

    N-Oxylpiperidyl-4-acetic acids (I) and (II) yielded mixed anhydrides, hydroxysuccinimide esters, and isocyanates which may be used as acylating or carbamoylating spin labels.

     
  2. 2.

    The oxidation of N-oxylpiperidylacetic acids (I) and (II) by chlorine and N2O4 yields stable N-oxopiperidylacetic acid salts.

     

Keywords

Oxidation Ester Chlorine Anhydride Isocyanate 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

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    E. G. Rozantsev and V. D. Sholle, The Organic Chemistry of Free Radicals [in Russian], Khimiya, Moscow (1979), p. 207.Google Scholar
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    R. I. Zhdanov, Paramagnetic Models of Biologically Active Compounds [in Russian], Nauka, Moscow (1981), p. 115.Google Scholar
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    E. S. Nikitskaya, E. I. Levkoeva, V. S. Usovskaya, L. N. Yakhontov, and M. V. Rubtsov, Khim. Geterotsikl. Soedin., 230 (1971).Google Scholar
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    A. B. Shapiro, K. Baimagambetov, M. G. Gol'dfel'd, and É. G. Rozantsev, Zh. Org. Khim.,8, 2263 (1972).Google Scholar
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    V. D. Sen', V. A. Golubev, and N. N. Efremova, Izv. Akad. Nauk SSSR, Ser. Khim., 61 (1982).Google Scholar
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    E. Stern and K. Timmons, Electronic Absorption Spectroscopy in Organic Chemistry [Russian translation], Mir, Moscow (1974), p. 54.Google Scholar

Copyright information

© Plenum Publishing Corporation 1984

Authors and Affiliations

  • V. D. Sen'
    • 1
  • E. V. Kapustina
    • 1
  • V. A. Golubev
    • 1
  1. 1.Institute of Chemical PhysicsAcademy of Sciences of the USSR, Chernogolovka BranchUSSR

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