Conclusions
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1.
The catalytic activity of heteropoly acids (HPA) in the reaction for the electrophilic addition of AcOH to 1-hexene is slightly dependent on the composition of the HPA and substantially exceeds the activity of H2SO4. The catalytic activity correlates with the dissociation constants of the acids.
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2.
The activity of the W HPA is higher than that of the Mo HPA due to the reduction of the Mo HPA during reaction, which leads to a decrease in their dissociation constants.
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Literature cited
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1651–1654, July, 1982.
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Kulikov, S.M., Kozhevnikov, I.V. Rate of electrophilic addition of acetic acid to 1-hexene when catalyzed by heteropoly acids. Russ Chem Bull 31, 1470–1472 (1982). https://doi.org/10.1007/BF00954182
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DOI: https://doi.org/10.1007/BF00954182