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Hydration of 3-methyl-3-norcarene epoxides under acid and basic catalysis conditions

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

The hydration of the cis- and trans-epoxides of 3-methyl-3-norcarene under acid catalysis conditions is characterized by a retention of the bicyclo[4.1.0]heptane structure and cleavage of the tertiary C-O bond of the epoxide rings; a regiospecificity of the opening is not observed under alkaline conditions.

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Literature cited

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Branch of the Academy of Sciences of the USSR, USSR

    É. Kh. Kazakova, L. N. Surkova & S. V. Andreeva

Authors
  1. É. Kh. Kazakova
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  2. L. N. Surkova
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  3. S. V. Andreeva
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1636–1638, July, 1982.

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Kazakova, É.K., Surkova, L.N. & Andreeva, S.V. Hydration of 3-methyl-3-norcarene epoxides under acid and basic catalysis conditions. Russ Chem Bull 31, 1456–1458 (1982). https://doi.org/10.1007/BF00954175

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  • DOI: https://doi.org/10.1007/BF00954175

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