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Reaction of 6, 8-di-tert-butylspiro[4,5]deca-1-oxa-5,8-diene-2,7-dione with acid agents

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The action of acid agents on 6, 8-di-tert-butylspiro[4.5]deca-1-oxa-5,8-diene-2,7-dione results in the initial opening of the lactone ring with a retention of the cyclohexadiene structure, and then the isomerization of the thus formed carbonium ion with migration of the carbonium ion center in two directions, and specifically in the six-membered ring and in the side chain.

  2. 2.

    The migration direction of the intermediately formed carbonium ion depends on the temperature.

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Literature cited

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Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow

    A. A. Volod'kin, R. D. Malysheva & V. V. Ershov

Authors
  1. A. A. Volod'kin
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  2. R. D. Malysheva
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  3. V. V. Ershov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1633–1635, July, 1982.

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Volod'kin, A.A., Malysheva, R.D. & Ershov, V.V. Reaction of 6, 8-di-tert-butylspiro[4,5]deca-1-oxa-5,8-diene-2,7-dione with acid agents. Russ Chem Bull 31, 1454–1456 (1982). https://doi.org/10.1007/BF00954174

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  • DOI: https://doi.org/10.1007/BF00954174

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