Conclusions
-
1.
In the reaction of PCl5 with 1,2-bis(hydroxymethyl)-o-carborane, the OH group is not replaced by chlorine, but 2(2′)-chloro-5,6,5′,6′-di(1″,2″-o-carborano)-1,3,1′,3′-tetraoxa-2, 2′-spiro-2(2′)-phosphorepane and 3,4-(1′,2′-o-carborano)oxolane are formed.
-
2.
The reaction of (C6H5O)3PX2 (X=Cl, Br) with 1,2-bis(hydroxymethyl)-o-carborane produces 3,4-(1′,2′-o-carborano)oxolane.
-
3.
The reaction of SOCl2 with 1, 2-bis(hydroxymethyl)-o-carborane in the presence of pyridine gives 2-oxo-1,3-oxa -5,6-(1′,2′-o-carborano)-2-thiaepane.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
Literature cited
L. I. Zakharkin, V. A. Brattsev, and Yu. A. Chapovskii, Zh. Obshch. Khim.,35, 2160 (1965).
F. Ramirez, A. J. Bigler, and C. P. Smith, Tetrahedron,24, 5041 (1968).
L. I. Zakharkin, A. I. Kovredov, A. V. Kazantsev, and M. G. Meiramov, Zh. Obshch. Khim.,51, 357 (1981).
L. I. Zakharkin, V. A. Brattsev, and V. I. Stanko, Zh. Obshch. Khim.,36, 886 (1966).
D. Grafstein, J. Bobinski, and J. Dvorak, Inorg. Chem.,2, 1120 (1963).
Author information
Authors and Affiliations
Additional information
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1603–1605, July, 1982.
Rights and permissions
About this article
Cite this article
Kazantsev, A.V., Meiramov, M.G., Kovredov, A.I. et al. Reaction of some halogen derivatives of phosphorus and sulfur with 1,2-bis(hydroxymethyl)-o-carborane. Russ Chem Bull 31, 1425–1427 (1982). https://doi.org/10.1007/BF00954165
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00954165