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Nucleophilic condensation of octafluoroisobutylene with tetrafluoroethylene

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

A CsF-catalyzed condensation of octafluoroisobutylene with tetrafluoroethylene leads to perfluoro-2,6,6-trimethyl-2-heptene as a result of a combined addition of perfluoro-tert-butyl anion and octafluoroisobutylene to the multiple bond of tetrafluoroethylene.

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Literature cited

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Additional information

Preliminary communication, see [1].

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1586–1590, July, 1982.

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Postovoi, S.A., Mysov, E.I., Zeifman, Y.V. et al. Nucleophilic condensation of octafluoroisobutylene with tetrafluoroethylene. Russ Chem Bull 31, 1409–1413 (1982). https://doi.org/10.1007/BF00954161

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  • DOI: https://doi.org/10.1007/BF00954161

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