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Kinetics of N-nitration of N-(nitroso)-nitroalkylamines by concentrated DNO3

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    In the N-nitration of N-(nitroso)nitroalkylamines by concentrated deuteronitric acid, a significant kinetic isotope effect is observed for bis(2,2-dinitropropyl)-N-nitrosoamine and bis(2,2-dinitrobutyl)-N-nitrosoamine. In the case of bis(2-fluoro-2,2-dinitroethyl)-N-nitrosoamine, the value of kH/kD is quite small.

  2. 2.

    The observed difference in the kinetic H/D isotope effects is explained by the mechanisms of conversion of the N-nitrosoamines, and it is related to the influence of the nitroalkyl substituants.

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Literature cited

  1. E. M. Sogomonyan, R. G. Gafurov, B. L. Korsunskii, and L. T. Eremenko, Izv. Akad. Nauk SSSR, Ser. Khim., 1508 (1981).

  2. R. G. Gafurov, E. M. Sogomonyan, and L. T. Eremenko, Izv. Akad. Nauk SSSR, Ser. Khim., 2606 (1971).

  3. R. G. Gafurov, E. M. Sogomonyan, A. F. Zholudev, and L. T. Eremenko, Izv. Akad. Nauk SSSR, Ser. Khim., 1648 (1978).

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Authors and Affiliations

  1. Branch of the Institute of Chemical Physics, Academy of Sciences of the USSR, Chernogolovka

    E. M. Sogomonyan, R. G. Gafurov, B. L. Korsunskii & L. T. Eremenko

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  1. E. M. Sogomonyan
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  2. R. G. Gafurov
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  3. B. L. Korsunskii
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  4. L. T. Eremenko
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1488–1490, July, 1982.

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Sogomonyan, E.M., Gafurov, R.G., Korsunskii, B.L. et al. Kinetics of N-nitration of N-(nitroso)-nitroalkylamines by concentrated DNO3 . Russ Chem Bull 31, 1327–1329 (1982). https://doi.org/10.1007/BF00954147

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  • DOI: https://doi.org/10.1007/BF00954147

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