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Catalytic activity of palladium complexes supported on silica gels modified by tertiary amines and quaternary ammonium bases in hydrogenation reactions

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Palladium complexes supported on silica gel modified by

    ,

    , and CH2-N(CH2COOH)5 groups catalyze the hydrogen and isomerization of the double bond in allylbenzene.

  2. 2.

    Going from a monodentate ligand to completely substituted ligands leads to a decrease in the activity of the palladium complexes supported on silica gel.

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Literature cited

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    V. Z. Sharf, M. A. Nesterov, L. P. Finn & I. B. Slinyakova

  2. L. V. Pisarzhevskii Institute of Physical Chemistry, Academy of Sciences of the Ukrainian SSR, Kiev

    V. Z. Sharf, M. A. Nesterov, L. P. Finn & I. B. Slinyakova

Authors
  1. V. Z. Sharf
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  2. M. A. Nesterov
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  3. L. P. Finn
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  4. I. B. Slinyakova
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2384–2386, October, 1984.

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Sharf, V.Z., Nesterov, M.A., Finn, L.P. et al. Catalytic activity of palladium complexes supported on silica gels modified by tertiary amines and quaternary ammonium bases in hydrogenation reactions. Russ Chem Bull 33, 2178–2180 (1984). https://doi.org/10.1007/BF00954112

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  • DOI: https://doi.org/10.1007/BF00954112

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