Conclusions
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1.
This is the first report of a gas solubility maximum in a nonaqueous electrolyte solution. The argon solubility maximum corresponds to a minimum for entropy losses due to the formation of cavities in the solvent.
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2.
The concept of a “limiting solvophobic effect temperature” was proposed.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2373–2376, October, 1984.
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Krestov, G.A., Vinogradov, V.I. & Sergeev, E.N. Special features of the solubility of argon in solvents with a three-dimensional hydrogen bond framework. Russ Chem Bull 33, 2168–2171 (1984). https://doi.org/10.1007/BF00954108
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DOI: https://doi.org/10.1007/BF00954108