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Reaction of esters of N-butyl-N-isobutenylamido- and bis(N-butyl-N-isobutenylamido)phosphorus acids with oxygen and halogen-containing compounds

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Dialkyl N-butyl-N-isobútenylamidophosphites are readily oxidized by oxygen, react with methyl iodide to form the corresponding methyl phosphonates, and react with acetyl chloride to give a dialkyl chlorophosphite and N-butyl-N-isobutenylacetamide.

  2. 2.

    Ethyl and triethylsilyl bis (N-butyl-N-isobutenylamido)phosphites react with carbon tetrachloride to form bis(N-butyl-N-isobutenylamido)chlorophosphate and 1,1,1-trichloropropane and trimethyltrichloromethylsilane, respectively.

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Literature cited

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Branch, Academy of Sciences of the USSR, USSR

    A. M. Kibardin, P. I. Gryaznov, T. Kh. Gazizov & A. N. Pudovik

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  1. A. M. Kibardin
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  2. P. I. Gryaznov
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  3. T. Kh. Gazizov
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  4. A. N. Pudovik
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2370–2373, October, 1984.

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Kibardin, A.M., Gryaznov, P.I., Gazizov, T.K. et al. Reaction of esters of N-butyl-N-isobutenylamido- and bis(N-butyl-N-isobutenylamido)phosphorus acids with oxygen and halogen-containing compounds. Russ Chem Bull 33, 2166–2168 (1984). https://doi.org/10.1007/BF00954107

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  • DOI: https://doi.org/10.1007/BF00954107

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