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Thermal decomposition of dimeric 9-tungstenophosphoric acid solvates with lower ketones

  • S. V. Kiselev
  • N. S. Ovchinnikova
  • V. F. Chuvaev
  • L. T. Zhuravlev
  • V. I. Spitsyn
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Conclusions

  1. 1.

    The nature of the catalytic transformation of acetone and methyl ethyl ketone upon the thermal decomposition of their solvates with dimeric 9-tungstenophosphoric acid is similar. Oxidation products consisting of acids and carbon dioxide are released initially followed by products of reduction and condensation (C3-C4 hydrocarbons and aromatic hydrocarbons). Then cracking products of the hydrocarbons formed, namely, methane, ethane, and water are detected.

     
  2. 2.

    Substitution of methyl for ethyl in the ketone causes a significant reduction in the velocity of the catalytic reaction.

     

Keywords

Oxidation Methyl Methane Dioxide Ethyl 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

  1. 1.
    I. N. Pinchuk, V. F. Chuvaev, N. S. Ovchinnikov, L. T. Zhuravlev, and V. I. Spitsyn, Izv. Akad. Nauk SSSR, Ser. Khim., 798 (1982).Google Scholar
  2. 2.
    V. F. Chuvaev, I. N. Pinchuk, Z. M. Plotnikova, and V. I. Spitsyn, Izv. Akad. Nauk SSSR, Ser. Khim., 2620 (1982).Google Scholar
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    S. V. Kiselev, Dissertation, Moscow (1983).Google Scholar
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    A. P. Gai, G. A. Gerasimova, V. V. Gubin, L. T. Zhuravlev, S. A. Kiselev, L. N. Nikitin, and N. P. Sokolova, Abstracts of the 2nd All-Union Conference on the Automation of Chemical Analysis [in Russian], Moscow (1980), p. 59.Google Scholar
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    V. F. Chuvaev, A. I. Gasanov, and V. I. Spitsyn, USSR Inventor's Certificate No. 550,373; Byull. Izobret., No. 10 (1977).Google Scholar
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    V. N. Ipatiett and C. B. Linn, US Patent No. 2.4296 (1944).Google Scholar

Copyright information

© Plenum Publishing Corporation 1985

Authors and Affiliations

  • S. V. Kiselev
    • 1
    • 2
  • N. S. Ovchinnikova
    • 1
    • 2
  • V. F. Chuvaev
    • 1
    • 2
  • L. T. Zhuravlev
    • 1
    • 2
  • V. I. Spitsyn
    • 1
    • 2
  1. 1.Institute of Physical ChemistryAcademy of Sciences of the USSRMoscow
  2. 2.N. I. Pirogov Second Moscow Medical InstituteUSSR

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