Conclusions
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1.
Arylation of anions by diarylhalonium fluoroborates under conditions of interphase catalysis proceeds more rapidly than in homogeneous media and as a rule in higher yield of the desired products.
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2.
The rules for the influence of substituents in the aromatic ligands of the iodoniura salts on their reactivity are retained on going over from homogeneous media to a two-phase system.
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3.
The yield of O-phenylation products grew in the series\(Ph_2 \mathop I\limits^ +< Ph_2 \mathop {Br}\limits^ +< Ph_2 \mathop {Cl}\limits^ + \) in the reaction of diphenylhalonium cations with the benzenesulfinate anion.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2332–2338, October, 1984.
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Grushin, V.V., Kantor, M.M., Tolstaya, T.P. et al. Arylation of anions with diarylhalonium fluoroborates under conditions of interphase catalysis. Russ Chem Bull 33, 2130–2135 (1984). https://doi.org/10.1007/BF00954097
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DOI: https://doi.org/10.1007/BF00954097