Reaction of isopropenylcyclopropane with arylsulfenyl chlorides and the isomerization of the adducts

  • Yu. B. Kal'yan
  • M. Z. Krimer
  • V. A. Smit
  • A. I. Lutsenko
Organic Chemistry
  • 20 Downloads

Conclusions

The addition of arylsulfenyl chlorides to isopropenylcyclopropane may, according to the polarity of the medium, proceed by normal addition at the double bond to give the 1,2-adducts, or by homoallyl rearrangement to give the corresponding homoprenyl chlorosulfides. Some bifunctional isoprenoid C6-synthones have been obtained.

Keywords

Chloride Adduct Double Bond Isoprenoid Normal Addition 

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Copyright information

© Plenum Publishing Corporation 1985

Authors and Affiliations

  • Yu. B. Kal'yan
    • 1
    • 2
  • M. Z. Krimer
    • 1
    • 2
  • V. A. Smit
    • 1
    • 2
  • A. I. Lutsenko
    • 1
    • 2
  1. 1.N. D. Zelinskii Institute of Organic ChemistryAcademy of Sciences of the USSRMoscow
  2. 2.Institute of ChemistryAcademy of Sciences of the Moldavian SSRKishinev

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