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Cyclic homo- and codimerization of 1,2-dimethylenecyclobutane with 1,3-dienes catalyzed by nickel complexes

  • Organic Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Cyclic homo- and cooligomerization of 1,2-dimethylenecyclobutane with butadiene, isoprene, piperylene, and cyclopropylbutadienes in the presence of three-component catalysts based on nickel were studied for the first time. The conditions for the preparation of previously unknown bi- and tricyclic hydrocarbons with four-carbon rings with high yields were determined.

  2. 2.

    1,2-Dimethylenecyclobutane retains the cyclobutane ring in conditions of homogeneous catalytic transformations and resembles the simplest 1,3-dienes with respect to the reactivity in these reactions.

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Authors and Affiliations

  1. Institute of Chemistry, Bashkir Branch, Academy of Sciences of the USSR, Ufa

    U. M. Dzhemilev, R. I. Khusnutdinov, N. A. Shchadneva, L. M. Khalilov, G. A. Tolstikov & O. M. Nefedov

  2. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    U. M. Dzhemilev, R. I. Khusnutdinov, N. A. Shchadneva, L. M. Khalilov, G. A. Tolstikov & O. M. Nefedov

Authors
  1. U. M. Dzhemilev
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  2. R. I. Khusnutdinov
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  3. N. A. Shchadneva
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  4. L. M. Khalilov
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  5. G. A. Tolstikov
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  6. O. M. Nefedov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2294–2299, October, 1984.

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Dzhemilev, U.M., Khusnutdinov, R.I., Shchadneva, N.A. et al. Cyclic homo- and codimerization of 1,2-dimethylenecyclobutane with 1,3-dienes catalyzed by nickel complexes. Russ Chem Bull 33, 2094–2099 (1984). https://doi.org/10.1007/BF00954089

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  • DOI: https://doi.org/10.1007/BF00954089

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