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Cotton-mouton constant and anisotropy of magnetic susceptibility of haloalkanes

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The principal semiaxes of the ellipsoid of diamagnetic susceptibility have been determined for the C-Cl, C-Br, and C-I bonds in haloalkanes.

  2. 2.

    The anisotropy of diamagnetic susceptibility of C-Hal bonds is negative, and it changes regularly in homologous series of compounds.

  3. 3.

    An empirical relationship has been established between the anisotropy of diamagnetic susceptibility and the electronic polarizability of C-Hal bonds in haloalkanes and halobenzenes.

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan' Branch, Academy of Sciences of the USSR, USSR

    S. G. Vul'fson & O. M. Dianova

Authors
  1. S. G. Vul'fson
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  2. O. M. Dianova
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2269–2274, October, 1984.

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Vul'fson, S.G., Dianova, O.M. Cotton-mouton constant and anisotropy of magnetic susceptibility of haloalkanes. Russ Chem Bull 33, 2070–2074 (1984). https://doi.org/10.1007/BF00954084

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  • DOI: https://doi.org/10.1007/BF00954084

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