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Primary photophysical and photochemical processes in solutions of 1,2,3,4-tetrahydkoquinolines

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Photoexcitation of solutions of 1,2,3,4-tetrahydroquinolines in the long-wave absorption band results in dissociation of the N-H bond in the lower triplet electron-excited state and the formation of aminyl radicals.

  2. 2.

    In photoirradiation of 1,2,3,4-tetrahydroquinolines in the short-wave absorption band, dissociation of the N-H bond from higher electron-excited states takes place.

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Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow

    Ya. N. Malkin, N. O. Pirogov, V. A. Kuz'min & I. E. Pokrovskaya

Authors
  1. Ya. N. Malkin
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  2. N. O. Pirogov
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  3. V. A. Kuz'min
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  4. I. E. Pokrovskaya
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2199–2204, October, 1984.

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Malkin, Y.N., Pirogov, N.O., Kuz'min, V.A. et al. Primary photophysical and photochemical processes in solutions of 1,2,3,4-tetrahydkoquinolines. Russ Chem Bull 33, 2005–2009 (1984). https://doi.org/10.1007/BF00954070

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  • DOI: https://doi.org/10.1007/BF00954070

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