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Kinetics of the reactions of radicals formed on pulsed electron radiation of cyclic alcohols in the liquid phase

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The kinetics, of quenching of the radicals formed under the effect of electron irradiation on liquid cyclohexanol and cyclododecanol in the absence of oxygen were investigated by pulsed radiolysis, and the absolute rate constants of α-hydroxycyclohexyl and α-hydroxycyclododecyl radicals in the 26–150°C and 85–135°C range were determined.

  2. 2.

    The rates of quenching of these α-hydroxycycloalkyl radicals are limited by the rates of their chemical reaction.

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Authors and Affiliations

  1. Institute of Electrochemistry, Academy of Sciences of the USSR, Moscow

    B. Ya. Ladygin, G. M. Zimina & A. A. Revina

  2. State Scientific-Research and Planning Institute of the Nitrogen Industry and Organic Synthesis Products, Moscow

    B. Ya. Ladygin, G. M. Zimina & A. A. Revina

Authors
  1. B. Ya. Ladygin
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  2. G. M. Zimina
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  3. A. A. Revina
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2194–2198, October, 1984.

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Ladygin, B.Y., Zimina, G.M. & Revina, A.A. Kinetics of the reactions of radicals formed on pulsed electron radiation of cyclic alcohols in the liquid phase. Russ Chem Bull 33, 2001–2004 (1984). https://doi.org/10.1007/BF00954069

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  • DOI: https://doi.org/10.1007/BF00954069

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